Chapter - 1
Fundamentals of Chemistry
EXERCISE
Multiple Choice Questions
Put a (✓) on the correct answer
1. Industrial chemistry deals with the manufacturing of compounds:
(a)
in the laboratory
(b)
on micro scale
(c) on commercial scale
(d) on economic scale
2. Which one of the following compounds can be separated by physical means?
(a) mixture
(b)
element
(c)
compound
(d) radical
3. The most abundant element occurring in the oceans is:
(a) oxygen
(b)
hydrogen
(c)
nitrogen
(d) silicon
4. Which one of the following elements is found in most abundance in the Earth’s crust?
(a)
oxygen
(b)
aluminium
(c)
silicon
(d) iron
5. The third abundant gas found in the Earth’s atmosphere is:
(a)
Carbon monoxide
(b)
oxygen
(c)
nitrogen
(d) argon
6. One amu (atomic mass unit) is equivalent to:
(a)
1.66 × 10-24 mg
(b) 1.66 × 10-24
g
(c)
1.66 × 10-24 kg
(d) 1.66 × 10-23 g
7. Which one of the following molecule is not tri-atomic?
(a) H2
(b)
O3
(c)
H2O
(d) CO2
8. The mass of one molecule of water is:
(a) 18 amu
(b)
18g
(c)
18mg
(d) 18kg
9. The molar mass of H2SO4 is:
(a) 98 g
(b)
98 amu
(c)
9.8 g
(d) 9.8 amu
10. Which one of the following is a molecular mass of O2 in amu?
(a) 32 amu
(b)
53.12 × 10-24 amu
(c)
1.92 × 10-25 amu
(d) 192.64 × 10-25 amu
11. How many number of moles are equivalent to 8 grams of CO2?
(a)
0.15
(b) 0.18
(c)
0.21
(d) 0.24
12. In which one of the following pairs has the same number of ions?
(a)
1 mole of NaCl and 1 mole of MgCl2
(b)
1/2
mole of NaCl and 1/2 mole of MgCl2
(c) 1/2 mole of NaCl and 1/3 mole of MgCl2
(d) 1/3 mole of NaCl and 1/2 mole of MgCl2
13. Which one of the following pairs has the same mass?
(a) 1 mole of CO and 1
mole of N2
(b)
1 mole of CO and 1 mole of CO2
(c)
1 mole of O2 and 1 mole of N2
(d)
1 mole of O2 and 1 mole of CO2
Short answer questions.
1. Define industrial chemistry and analytical chemistry.
Ans. Industrial Chemistry:
The branch of chemistry that deals with the manufacturing of chemical compounds on commercial scale is called industrial chemistry. It deals with the manufacturing of basic chemicals such as oxygen, chlorine, ammonia, caustic soda, nitric acid and sulphuric acid.
Analytical Chemistry:
Analytical chemistry is the branch of chemistry that deals with separation and analysis of a sample to identify its components. The separation is carried out prior to qualitative and quantitative analysis. This branch covers food, water, environmental and clinical analysis.
2. How can you differentiate between organic and inorganic chemistry?
Ans.
Organic
Chemistry |
Inorganic
Chemistry |
Organic
chemistry is the study of covalent compounds of carbon and hydrogen
(hydrocarbons) and their derivatives. |
Inorganic
chemistry deals with the study of all elements and their compounds except
those of compounds of carbon and hydrogen (hydrocarbons) and their
derivatives. |
This branch covers
petroleum, petrochemicals and pharmaceutical industries. |
This branch
covers the chemical industry such as glass, cement, ceramics and metallurgy
(extraction of metals from ores). |
Homogeneous
Mixtures |
Heterogeneous
Mixture |
Mixtures that
have uniform composition throughout are called homogeneous mixtures. |
Mixtures that
have not uniform composition throughout are called heterogeneous mixtures. |
For example: air, gasoline, ice cream, etc. |
For example:
soil, rock, wood, etc. |
1 amu = 1.66 × 10-24g
6. Define empirical formula with an example.
Ans. Empirical formula:
It is defined as the formula which represents the simplest whole number ratio of atoms present in a compound. Example: Glucose has simplest ratio 1:2:1 of carbon, hydrogen and oxygen, respectively. Hence, its empirical formula is CH2O.
7. State three reasons why do you think air is a mixture and water a compound?
Ans.
Air is a
mixture:
i.
It shows the properties of its constituents.
ii.
Its constituents can be separated by
physical methods.
iii.
It does not have any chemical formula.
Water is a compound:
i.
It shows different properties for its
constitutes.
ii.
Its constituents cannot be separated by
physical methods.
iii. It has fixed chemical formula H2O
8. Explain why are hydrogen and oxygen considered elements whereas water as a compound.Soft drink is a
mixture:
i.
It shows the properties of its constituents.
ii.
Its constituents can be separated by
physical methods.
iii.
It does not have any chemical formula.
Water is a
compound:
i.
It shows different properties for its
constitutes.
ii.
Its constituents cannot be separated by
physical methods.
iii. It has fixed chemical formula H2O.
11. Classify the following into element, compound or mixture:i.
He
and H2
ii.
CO
and Co
iii.
Water
and milk
iv.
Gold
and brass
v. Iron and steel
Element |
Compound |
Mixture |
He, Co, Gold
and Iron. |
H2,
CO, Water. |
Milk, Brass
and Steel. |
1 amu = 1.66 × 10-24g
Need: For very small particles ‘amu’ is used rather than ‘g’ or ‘kg’ because it is convenient to measure masses of such small particles like electrons, protons and neutrons.
13. State the nature and name of the substance formed by combining the following:i.
Zinc
+ Copper
ii.
Water
+ Sugar
iii.
Aluminium
+ Sulphur
iv. Iron + Chromium + Nickel
Ans.
Substance |
Nature |
Name |
Zinc + Copper |
Alloy
(mixture) |
Brass |
Water + Sugar |
Solution
(mixture) |
Aqueous
solution of sugar |
Aluminium +
Sulphur |
Compound |
Aluminium
sulphide |
Iron +
Chromium + Nickel |
Alloy
(mixture) |
Nichrome |
H2O, NaCl, KI, H2SO4
Homoatomic
Molecule |
Heteroatomic
Molecule |
A molecule
containing same type of atoms, is called homoatomic molecule. |
A molecule
consists of different kinds of atoms, it is called heteroatomic molecule. |
For
example:
hydrogen (H2), ozone (O3), sulphur (S8) and
phosphorus (P4), etc. |
For
example: CO2,
H2O and NH3, etc. |
No. of moles of hydrogen in 1 mole of HCl = 1 mole
No. of moles of hydrogen in 2 mole of HCl = 2 moles
Whereas no. of moles of hydrogen in 1 mole of NH3
= 3 moles
Hence 1 mole of NH3 contains 3 moles of
hydrogen and will have more hydrogen atoms than 2 moles of hydrogen present in
2 moles of HCl.
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